Nitrogen isotopic evolution of carbonaceous matter during metamorphism: Methodology and preliminary results - Bioemco Accéder directement au contenu
Article Dans Une Revue Chemical Geology Année : 2006

Nitrogen isotopic evolution of carbonaceous matter during metamorphism: Methodology and preliminary results

Résumé

Nitrogen content and isotopic composition of carbonaceous-rich metasediments were determined by on-line and sealed-tube combustion using ultra-high vacuum line and static mass spectrometer adapted to analyse nitrogen nanomoles. Accurate mea¬surements showed that nitrogen amount released by on-line combustion technique was underestimated to various extents. As a result, the nitrogen isotopic composition was not correctly determined. In contrast, sealed-tube combustion appeared to yield the most reproducible and accurate measurements, except for nitrogen depleted carbonaceous matter (semi-graphite to graphite transition) containing less than around 60 ppm of nitrogen, which were contaminated during their extraction from the rock. In view of that, a preliminary sealed-tube investigation of the organic nitrogen content and isotopic composition in a homogenous series of low-grade metasediments was undertaken: in spite of an important nitrogen loss, the carbonaceous matter nitrogen isotopic composition remains about the same during the meta-anthracite and semi-graphitisation stages. Inferences on the process of organic nitrogen mineralization during carbonaceous matter metamorphism can be drawn and several paleo-biogeochemical implications envisaged.

Domaines

Géochimie
Fichier principal
Vignette du fichier
ADER-HAL.pdf (392.08 Ko) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)

Dates et versions

bioemco-00144850 , version 1 (05-05-2007)

Identifiants

Citer

Magali Ader, Pierre Cartigny, Jean-Paul Boudou, Jae-Ho Oh, Eddy Petit, et al.. Nitrogen isotopic evolution of carbonaceous matter during metamorphism: Methodology and preliminary results. Chemical Geology, 2006, 232 (3-4), pp.152-169. ⟨10.1016/j.chemgeo.2006.02.019⟩. ⟨bioemco-00144850⟩
379 Consultations
460 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More